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Egyptians may have pioneered the field of deodorants. (They used cinnamon)
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In Roman - some warned women not to carry goats under their arms.( That stinks)
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The first modern antiperspirant - was EverDry. It hit drugstores in 1903 - and was so strong it ate through clothing.)

More fun facts about Deodorant:
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Fun Facts about your Deodorant....